MFN: 01
Responsible Party
Name: TITAN INTERNATIONAL
Address: 205 CHESTER AVENUE, SUITE 100
City: MOORESTOWN NJ 08057
Info Phone Number: 800-435-4644
Emergency Phone Number: 800-435-4644
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Item Description Information
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Item Manager: S9G
Item Name: SULFURIC ACID,ACS
Specification Number: O-C-265C
Type/Grade/Class: NONE
Unit of Issue: BT
Quantitative Expression: 00000000005PT
UI Container Qty: 1
Type of Container: BOTTLE
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Ingredients
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Cas: 7664-93-9
RTECS #: WS5600000
Name: SULFURIC ACID
% low Wt: 95.
% high Wt: 98.
OSHA PEL: 1 MG/M3
ACGIH TLV: 1 MG/M3
ACGIH STEL: 3 MG/M3
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
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Health Hazards Data
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LD50 LC50 Mixture: ORAL-RAT LD50: 2140 MG/KG
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
IARC: YES
Effects of Exposure: ACUTE: MAY BE FATAL IF SWALLOWED. HARMFUL IF INHALED OR
ABSORBED THROUGH SKIN. MATEIAL IS EXTREMELY DESTRUCTIVE TO TISSUE OF THE
MUCOUS MEMBRANES AND UPPER RESPIRATORY TRACT, EYES, AND SKIN. INHALATIO N MAY
BE FATAL AS A RESULT OF SPASM, INFLAMMATION AND EDEMA OF THE LARYNX AND
BRONCHI, CHEMICAL PNEUMONITIS, AND PULMONARY EDEMA. CHRONIC EFFECTS:
CARCINOGEN.
Explanation Of Carcinogenicity: THE INTERNATIONAL AGENCY FOR RESEARCH ON CANCER
(IARC) HAS DETEMINED THAT OCCUPATIONAL EXPOSURE TO STRONG-INORGANIC-ACID
MISTS CONTAINING SULFURIC ACID IS CARCINOGENIC TO HUMANS (GROUP 1).
Signs And Symptions Of Overexposure: SYMPTOMS OF EXPOSURE MAY INCLUDE BURNING
SENSATION, COUGHING, WHEEZING, LARYNGITIS, SHORTNESS OF BREATH, HEADACHE,
NAUSEA, VOMITING, TISSUE DESTRUCTION, INFLAMMATION AND EDEMA OF THE LARYNX
AND BRONCH I, CHEMICAL PNEUMONITIS, PULMONARY EDEMA.
First Aid: IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES OR SKIN WITH COPIOUS
AMOUNTS OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING
AND SHOES. ASSURE ADEQUATE FLUSHING OF THE EYES BY SEPARAT ING THE EYELIDS
WITH FINGERS. IF INHALED, REMOVE TO FRESH AIR. IF NOT BREATHING GIVE
ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT GIVE OXYGEN. IF SWALLOWED,
WASH OUT MOUTH WITH WATER PROVIDED PER SON IS CONSCIOUS. CALL A PHYSICIAN
IMMEDIATELY. WASH CONTAMINATED CLOTHING BEFORE REUSE. DISCARD CONTAMINATED
SHOES.
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Handling and Disposal
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Spill Release Procedures: EVACUATE AREA. WEAR SELF-CONTAINED BREATHING
APPARATUS, RUBBER BOOTS AND HEAVY RUBBER GLOVES. COVER WITH DRY-LIME, SAND,
OR SODA ASH. PLACE IN COVERED CONTAINERS USING NON-SPARKING TOOLS AND
TRANSPORT OUTDOORS. VENTILATE AREA AND WASH SPILL SITE AFTER MATERIAL PICKUP
IS COMPLETE. AVOID INHALATION.
Neutralizing Agent: DRY LIME, SODA ASH.
Waste Disposal Methods: OBSERVE ALL FEDERAL, STATE AND LOCAL ENVIRONMENTAL
REGULATIONS. SMALL AMOUNTS: CAUTIOUSLY ADD TO LARGE STIRRED EXCESS OF WATER
(HEAT AND FUMES CAN BE CONTROLLED BY RATE OF ADDITION). ADJUST PH TO NEUT
RAL, SEPARATE INSOLUBLE SOLIDS OR LIQUIDS AND PACKAGE FOR DISPOSAL. FLUSH
AQUEOUS SOLUTION DOWN DRA IN WITH PLENTY OF WATER.
Handling And Storage Precautions: KEEP TIGHTLY CLOSED. DO NOT STORE NEAR, NOR
ALLOW CONTACT WITH, CLOTHING AND OTHER COMBUSTIBLE MATERIAL. DO NOT ALLOW
CONTACT WITH WATER. VERY HYGROSCOPIC. STORE IN A COOL DRY PLACE. DO NOT
BREATHE VA POR. AVOID CONTACT WITH EYES, SKIN AND CLOTHING. WASH THOROUGHLY
AFTER HANDLING.
Other Precautions: STORE AWAY FROM INCOMPATIBLES. USE ONLY IN A CHEMICAL HOOD.
AVOID PROLONGED OR REPEATED EXPOSURE.
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Fire and Explosion Hazard Information
=======================================================
Flash Point Text: NONCOMBUSTIBLE
Extinguishing Media: USE EXTINGUISHING MEDIA APPROPRIATE TO SURROUNDING FIRE
CONDITIONS. DO NOT USE WATER.
Fire Fighting Procedures: WEAR SELF-CONTAINED BREATHING APPARATUS AND
PROTECTIVE CLOTHING TO PREVENT CONTACT WITH SKIN AND EYES. STRONG OXIDIZER.
Unusual Fire/Explosion Hazard: EMITS TOXIC FUMES UNDER FIRE CONDITIONS. CONTACT
WITH OTHER MATERIAL MAY CAUSE FIRE.
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Control Measures
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Respiratory Protection: WEAR APPROPRIATE NIOSH/MSHA-APPROVED RESPIRATOR.
Ventilation: USE ONLY IN A CHEMICAL FUME HOOD.
Protective Gloves: WEAR CHEMICAL-RESISTANT GLOVES.
Eye Protection: WEAR SAFETY GOGGLES. FACESHIELD (8-INCH MINIMUM).
Other Protective Equipment: WEAR PROTECTIVE CLOTHING. USE ONLY IN A CHEMICAL
FUME HOOD. PROVIDE SAFETY SHOWER AND EYE BATH.
Work Hygienic Practices: AVOID CONTACT WITH EYES, SKIN AND CLOTHING. DO NOT
BREATHE VAPOR. AVOID PROLONGED OR REPEATED EXPOSURE. WASH THOROUGHLY AFTER
HANDLING. CARCINOGEN, POISON, AND CORROSIVE.
Supplemental Safety and Health: KEEP TIGHTLY CLOSED. DO NOT STORE NEAR, NOR
ALLOW CONTACT WITH, CLOTHING AND OTHER COMBUSTRIBLE MATERIAL. DO NOT ALLOW
CONTACT WITH WATER. VERY HYGROSCOPIC, STORE IN A COOL DRY PLACE.
=======================================================
Physical/Chemical Properties
=======================================================
HCC: C1
Vapor Pres: 1MM @145.8C
Vapor Density: <.3@25C
Spec Gravity: 1.840
Appearance and Odor: VISCOUS COLORLESS LIQUID.
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Reactivity Data
=======================================================
Stability Condition To Avoid: DO NOT ALLOW WATER TO ENTER CONTAINER BECAUSE OF
VIOLENT REACTION.
Materials To Avoid: BASES, HALIDES, ORGANIC MATERIALS, FINELY POWDERED METALS,
PROTECT FROM MOISTURE.
Hazardous Decomposition Products: HAZARDOUS COMBUSTION OR DECOMPOSITION
PRODUCTS: SULFUR OXIDES
=======================================================
Toxicological Information
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Toxicological Information: IARC HAS DETERMINED THAT OCCUPATIONAL EXPOSURE TO
STRONG-INORGANIC-ACID MISTS CONTAINING SULFURIC ACID IS CARCINOGENIC TO
HUMANS (GROUP 1). IRRITATION DATA: EYE- RBT 250 UG SEV, AJOPAA 29, 1363,46;
EY E-RBT 5 MG/ 30S, RINSE SEV, TXCYAC 23,281,82. TOXICITY DATA: UNR-MAN-135
MG/KG, 85DCAI 2,73,70. ORAL-RAT LD50: 2140 MG/KG, AIHAAP 30,470,69. IHL-RAT
LC50: 510 MG/M3/2H, 85GMAT - 107,82. INH-MUS LC50: 320 MG/M3/2H, 85GMAT -
107, 82. IHL-GPG LC50: 18 MG/M3, ME;AAD 45, 590,54. ONLY SELECTED REGISTRY OF
TOXIC EFFECTS OF CHEMICAL SUBSTANCES (RTECS) DATA IS PRESENTED HERE. SEE
ACTUAL ENTRY IN RTECS FOR COMPLETE INFORMATION.
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Ecological Information
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Ecological: DATA NOT YET AVAILABLE.
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MSDS Transport Information
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Transport Information: CONTACT ALDRICH CHEMICAL COMPANY FOR TRANSPORTATION
INFORMATION.
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Regulatory Information
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Sara Title III Information: THIS PRODUCT IS SUBJECT TO SARA SECTION 313
REPORTING REQUIREMENTS
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Other Information
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Other Information: EUROPEAN INFORMATION: EC INDEX NO. 016-020-00-8. OXIDIZING.
TOXIC, R 35, CAUSES SEVERE BURNS,S 26, IN CASE OF CONTACT WITH EYES, RINSE
IMMEDIATELY WITH PLENTY OF WATER AND SEEK MEDICAL ATTENTION.,S 30 , NEVER ADD
WATER TO THIS PRODUCT, S 45,IN CASE OF ACCIDENT OR IF YOU FEEL UNWELL, SEEK
MEDICAL ADVICE IMMEDIATELY (SHOW LABEL WHERE POSSIBLE). REVIEWS, STANDARDS,
AND REGULATIONS, OEL-MAK, ACGIH TLV- TWA 1 MG/M3; STEL 3 MG/M3, 85INA8
6,1461,91. IARC CANCER REVIEW: HUMAN SUFFICIENT EVIDENCE, IMEMDT 54, 41, 92.
IRAC CANCER REVIEW: GROUP 1, IMEMDT 54, 41,92. EPA FIFRA 1988 PESTICIDE
SUBJECT TO REGIST RATION OR RE-REGISTRATION.
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Transportation Information
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Responsible Party Cage: UO291
Trans ID NO: 156032
Product ID: SULFURIC ACID, 95-98% A.C.S. REAGENT
MSDS Prepared Date: 04/01/1996
Review Date: 02/20/2001
MFN: 1
Net Unit Weight: 9 LB
Multiple KIT Number: 0
Unit Of Issue: BT
Container QTY: 1
Type Of Container: BOTTLE
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Detail DOT Information
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DOT PSN Code: NUC
DOT Proper Shipping Name: SULFURIC ACID
DOT PSN Modifier: WITH MORE THAN 51 PERCENT ACID
Hazard Class: 8
UN ID Num: UN1830
DOT Packaging Group: II
Label: CORROSIVE
Special Provision: A3,A7,B3,B83,B84,N34,T9,T27
Packaging Exception: 154
Non Bulk Pack: 202
Bulk Pack: 242
Max Qty Pass: 1 L
Max Qty Cargo: 30 L
Vessel Stow Req: C
Water/Ship/Other Req: 14
=======================================================
Detail IMO Information
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IMO PSN Code: OFJ
IMO Proper Shipping Name: SULPHURIC ACID
IMO PSN Modifier: ,WITH MORE THAN 51% ACID
IMDG Page Number: 8230
UN Number: 1830
UN Hazard Class: 8
IMO Packaging Group: II
Subsidiary Risk Label: -
EMS Number: 8-06
MED First Aid Guide NUM: 700
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Detail IATA Information
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IATA PSN Code: XIX
IATA UN ID Num: 1830
IATA Proper Shipping Name: SULPHURIC ACID
IATA PSN Modifier: WITH MORE THAN 51% ACID
IATA UN Class: 8
IATA Label: CORROSIVE
UN Packing Group: II
Packing Note Passenger: 809
Max Quant Pass: 1L
Max Quant Cargo: 30L
Packaging Note Cargo: 813
=======================================================
Detail AFI Information
=======================================================
AFI PSN Code: XIX
AFI Proper Shipping Name: SULPHURIC ACID
AFI PSN Modifier: WITH MORE THAN 51% ACID
AFI Hazard Class: 8
AFI UN ID NUM: UN1830
AFI Packing Group: II
Special Provisions: P4, A3, A7, N34
Back Pack Reference: A12.3
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HAZCOM Label
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Product ID: SULFURIC ACID, 95-98% A.C.S. REAGENT
Assigned IND: Y
Company Name: TITAN INTERNATIONAL
Street: 205 CHESTER AVENUE, SUITE 100
City: MOORESTOWN NJ
Zipcode: 08057
Health Emergency Phone: 800-435-4644
Label Required IND: Y
Date Of Label Review: 02/20/2001
Status Code: A
Label Date: 02/20/2001
Origination Code: F
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Severe
Contact Hazard: Severe
Fire Hazard: None
Reactivity Hazard: Moderate
Hazard And Precautions: ACUTE: MAY BE FATAL IF SWALLOWED. HARMFUL IF INHALED OR
ABSORBED THROUGH SKIN. MATERIAL IS EXTREMELY DESTRUCTIVE TO TISSUE OF THE
MUCOUS MEMBRANES AND UPPER RESPIRATORY TRACT, EYES, AND SKIN. INHALATI ON MAY
BE FATAL AS A RESULT OF SPASM, INFLAMMATION AND EDEMA OF THE LARYNX AND
BRONCHI, CHEMICAL PNEUMONITIS, AND PULMONARY EDEMA. CHRONIC EFFECTS:
CARCINOGEN.
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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